Source: Geophysical Research Letters
Earth’s inner core is dominated by iron, which can exist as a solid material in more than one crystallographic form. (This quality allows iron to combine with other elements to form alloys.) Iron’s most stable form at room temperature is the body-centered cubic (bcc) structure. At extremely high pressures, it is stable in its hexagonal close-packed (hcp) phase. Of considerable debate, however, is iron’s structure at the center of Earth. In a new study, Sun et al. get one step closer to an answer.
The deliberation centers on the melting temperatures of iron’s two phases at core pressures: 323 gigapascals at the inner core boundary and 360 gigapascals at the core center. Previous studies have struggled to estimate melting temperatures with any precision. The best guesses have had an uncertainty range of 500 K.
Researchers use two types of simulations of atomic interaction to estimate iron’s melting temperatures at the inner core: classical and ab initio. Both approaches have pros and cons, but neither has yet provided a clear answer. In the new study, scientists bridged the two simulation strategies to calculate the melting temperatures for hcp and bcc iron at Earth’s core.
They found that the hcp phase is iron’s stable phase at the inner core. The melting temperature of hcp iron is always higher than that of the bcc form, but that difference is very small. At pressures approximating the inner core boundary, the study reports a melting temperature of 6,357 ± 45 K for the hcp phase and 6,168 ± 80 K for the bcc phase. At pressures similar to the core center, the melting temperature was 6,692 ± 45 K for hcp and 6,519 ± 80 K for bcc.
The research offers new perspectives on the structure, evolution, and dynamics of Earth’s core. Future work, the scientists say, should include the effect of nickel and light elements in simulations of the inner core’s structure. (Geophysical Research Letters, https://doi.org/10.1029/2022GL102447, 2023)
—Aaron Sidder, Science Writer
Correction, 20 March 2023: An earlier version of this article incorrectly stated an uncertainty range in estimating the melting temperatures of iron’s two phases at core pressures. It is 500 K, not 440℉.