Photomicrographs of minerals.
Pedogenic carbonates form in soils with alternating moisture conditions, leading to calcite supersaturation, secondary carbonate precipitation, and accumulation. These carbonates also develop through interactions between organic and mineral components in the subaerial vadose environment. Organic-rich microcrystalline calcite grows around roots, creating distinctive casts called microcodiums (Gen 1). Over time, burial into the saturated zone below the water table and then deeper into the phreatic zone produces multiple generations of carbonates (Gen 2 and Gen3) with complex geometries and relationships. Understanding this fine structure turns out to be essential to obtaining valid U-Pb dates from these soil horizons. Credit: Aguirre Palafox et al. [2024], Figures 3 and 4(c,d)
Editors’ Highlights are summaries of recent papers by AGU’s journal editors.
Source: Geochemistry, Geophysics, Geosystems

Paleosols are key horizons in terrestrial sedimentary successions. They often comprise pedogenic carbonate accumulations whose geochemical properties can be used as proxies for reconstructing paleoclimate, measuring paleo-altitude, and assessing paleo-vegetation. However, the key to unlocking any geologic archive is age determination. Unfortunately, terrestrial successions are commonly very difficult to date, except for those including volcanic layers rich in zircons. Thus, the availability of other dating tools is crucial.

The trace amounts of uranium in calcite permit its use as a geochronometer. However, past attempts at dating pedogenic carbonates have yielded unsatisfactory results. This difficulty arises from factors such as low uranium content, high lead content, complex formation chemistry, multiple formation episodes, and the potential for post-formation chemical alteration.

Aguirre Palafox et al. [2024] provide a new strategy to date pedogenic carbonates that harnesses their microstratigraphy. Their analysis is based on a careful petrographic characterization that enables the reconstruction of the sequence in which the pedogenic carbonates formed. This strategy allows for the identification and exclusion of chemically altered material and the accurate interpretation of carbonate ages.

Citation: Aguirre Palafox, L. E., Möller, A., McLean, N. M., Ludvigson, G. A., Colombi, C. E., & Montañez, I. P. (2024). U-Pb geochronology of paleosol carbonate cements by LA-ICP-MS: A proof of concept and strategy for dating the terrestrial record. Geochemistry, Geophysics, Geosystems, 25, e2024GC011488. https://doi.org/10.1029/2024GC011488

—Maria Giuditta Fellin, Associate Editor, G-Cubed

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